Research Overview
Our mission is to design greener catalytic methods for the synthesis of commodity and specialty organics, and polymers. Green synthesis is an important objective for modern chemists. Driven by societal demands and fundamental interest, our group has been focusing on the development of more efficient catalysts for small molecule valorization and the utilization of carbon renewables. A special emphasis in our ongoing work is the use of carbon dioxide, terpenes and other renewable carbon-sourced feedstock such as fatty acids, sugars and alike. Our research relies on the use of effective and new metal/organo-catalytic solutions. Examples include in-house developed Al- and Fe-centered aminotriphenolate complexes, and polyphenolic or N-heterocyclic compounds. Catalytic processes based on these catalysts have advanced the preparation of fine chemicals, pharma-relevant compounds and novel materials based on biopolymers. In our ongoing efforts, we focus on processes that allow to control the chemo-, regio-, diastereo- and/or enantio-selectivity profiles while creating fundamental and commercial value. The recycling of generally considered low-value feedstock offers a way to contribute to a circular economy and reducing environmental / carbon footprints thus contributing to improved sustainability.
Prof. Arjan W. Kleij
