Research Overview
Our mission is to design greener catalytic methods for the synthesis of functional small molecules and polymers. Green synthesis is an important objective for modern chemists. Driven by societal demands and fundamental interest, our group has been focusing on the development of more efficient catalysts for the valorization of carbon renewables. A special emphasis in our ongoing work is the use of carbon dioxide, terpenes and feedstock such as fatty acids, sugars and other sources of biomass. Our research relies on the use of effective metal/organo-catalytic solutions. Examples include “in house” developed Al- and Fe-centered aminotriphenolate complexes, and polyphenolic or N-heterocyclic compounds. Catalytic processes based on these catalysts have helped us to advance the preparation of fine chemicals, pharma-relevant compounds and novel materials based on biopolymers. In our ongoing efforts, we focus on processes that entail high chemo-, regio-, diastereo- and/or enantio-selectivity control. The recycling of generally considered low-value (bio)feedstock contributes to a circular economy while reducing environmental / carbon footprints, and as such help to advance sustainable chemical synthesis.
Prof. Arjan W. Kleij
